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学科主题: Polymer Science
题名: A facile method for the preparation of thermally remendable cross-linked polyphosphazenes
作者: [Cheng, Xinjian ; Peng, Cheng ; Zhang, Daohong ; Liu, Shuzheng ; Zhang, Aiqing] S Cent Univ Nationalities, Sch Chem & Mat Sci, Wuhan 430074, Peoples R China ; [Huang, Hui ; Lian, Jiansheng] Chinese Acad Sci, S China Sea Inst Oceanol, LMB, Guangzhou 510301, Guangdong, Peoples R China
通讯作者: chxj606@163.com ; aiqingzhang_2000@sina.com
关键词: D-A reaction ; elastomers ; functional polyphosphazenes ; polyphosphazenes ; remendable ; synthesis
刊名: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
发表日期: 2013
卷: 51, 期:5, 页:1205-1214
部门归属: LMB
资助者: The authors thank the support by "Guangdong Natural Sicen Foundation (No. S201210009845) and "Fundamental Research Funds for Central Universities of China'' (South-central University for Nationalities, CZY10005).
摘要: Novel cross-linked polyphosphazenes with remendable capacity have been synthesized through the Diels-Alder reactions. Their structure and properties were characterized by NMR, FT-IR, GPC, DSC, TGA SEM, and polarizing microscope. The process of Diels-Alder reaction (D-A reaction) and retro-Diels-Alder reaction (retro-D-A reaction) have been investigated by FT-IR, UV, and DSC. The cross-linked polyphosphazenes exhibited remendable capability only need a thermal treatment when they were cut by blade, any other treatments such as additional monomer or catalyst, surface treatment or pressure were not needed. (c) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000314150900021
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.scsio.ac.cn/handle/344004/11068
Appears in Collections:中科院海洋生物资源可持续利用重点实验室_期刊论文

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Recommended Citation:
[Cheng, Xinjian; Peng, Cheng; Zhang, Daohong; Liu, Shuzheng; Zhang, Aiqing] S Cent Univ Nationalities, Sch Chem & Mat Sci, Wuhan 430074, Peoples R China; [Huang, Hui; Lian, Jiansheng] Chinese Acad Sci, S China Sea Inst Oceanol, LMB, Guangzhou 510301, Guangdong, Peoples R China.A facile method for the preparation of thermally remendable cross-linked polyphosphazenes,JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2013,51(5):1205-1214
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