Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity
Das, Subrata; Ranjani, Anandan; Gayathri, Loganathan; Saha, Subhasish; Pasan, Jorge; Dhanasekaran, Dharumadurai; Akbarsha, Mohammad Abdulkader; Maji, Milan; Biswas, Bhaskar; Biswas, B (reprint author), Raghunathpur Coll, Dept Chem, Purulia 723133, W Bengal, India.
2016
发表期刊JOURNAL OF CHEMICAL SCIENCES
卷号128期号:11页码:1755-1764
摘要A mononuclear cobalt(III) complex [Co(bpy)(2)Cl-2]NO(3)ai...2H(2)O (1) (bpy = 2,2(')-bipyridine) has been synthesized and crystallographically characterized. Self-assembly of the lattice water molecules from rectangular tetrameric water cluster interacts with nitrate anion along the c-axis forming a six membered hexagonal water-nitrate cluster. It presents a new mode of association of water molecules with nitrate molecules which is not predicted theoretically or found experimentally. The molecule effectively cleaves bacterial genomic DNA and shows important cytotoxicity against human hepatocarcinoma cell (HepG2).
部门归属[Das, Subrata; Biswas, Bhaskar] Raghunathpur Coll, Dept Chem, Purulia 723133, W Bengal, India; [Ranjani, Anandan; Gayathri, Loganathan; Saha, Subhasish; Dhanasekaran, Dharumadurai] Bharathidasan Univ, Dept Microbiol, Tiruchchirappalli 620024, Tamil Nadu, India; [Gayathri, Loganathan; Akbarsha, Mohammad Abdulkader] Bharathidasan Univ, Mahatma Gandhi Doerenkamp Ctr, Tiruchchirappalli 620024, Tamil Nadu, India; [Pasan, Jorge] Univ Valencia, Inst Ciencia Mol ICMol, Catedrat Jose Beltran 2, Valencia 46980, Spain; [Maji, Milan] Natl Inst Technol, Dept Chem, Mahatma Gandhi Ave, Durgapur 713209, W Bengal, India; [Saha, Subhasish] Chinese Acad Sci, South China Sea Inst Oceanol, Ctr Marine Microbiol, Guangzhou 510301, Guangdong, Peoples R China ; LMB
关键词Cobalt(Iii) Crystal Structure Supramolecular Chemistry Anticancer Activity Molecular Docking
学科领域Chemistry
文献类型期刊论文
条目标识符http://ir.scsio.ac.cn/handle/344004/15266
专题中科院海洋生物资源可持续利用重点实验室
通讯作者Biswas, B (reprint author), Raghunathpur Coll, Dept Chem, Purulia 723133, W Bengal, India.
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GB/T 7714
Das, Subrata,Ranjani, Anandan,Gayathri, Loganathan,et al. Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity[J]. JOURNAL OF CHEMICAL SCIENCES,2016,128(11):1755-1764.
APA Das, Subrata.,Ranjani, Anandan.,Gayathri, Loganathan.,Saha, Subhasish.,Pasan, Jorge.,...&Biswas, B .(2016).Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity.JOURNAL OF CHEMICAL SCIENCES,128(11),1755-1764.
MLA Das, Subrata,et al."Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity".JOURNAL OF CHEMICAL SCIENCES 128.11(2016):1755-1764.
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