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Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity
Das, Subrata; Ranjani, Anandan; Gayathri, Loganathan; Saha, Subhasish; Pasan, Jorge; Dhanasekaran, Dharumadurai; Akbarsha, Mohammad Abdulkader; Maji, Milan; Biswas, Bhaskar; Biswas, B (reprint author), Raghunathpur Coll, Dept Chem, Purulia 723133, W Bengal, India.
2016
Source PublicationJOURNAL OF CHEMICAL SCIENCES
Volume128Issue:11Pages:1755-1764
AbstractA mononuclear cobalt(III) complex [Co(bpy)(2)Cl-2]NO(3)ai...2H(2)O (1) (bpy = 2,2(')-bipyridine) has been synthesized and crystallographically characterized. Self-assembly of the lattice water molecules from rectangular tetrameric water cluster interacts with nitrate anion along the c-axis forming a six membered hexagonal water-nitrate cluster. It presents a new mode of association of water molecules with nitrate molecules which is not predicted theoretically or found experimentally. The molecule effectively cleaves bacterial genomic DNA and shows important cytotoxicity against human hepatocarcinoma cell (HepG2).
Department[Das, Subrata; Biswas, Bhaskar] Raghunathpur Coll, Dept Chem, Purulia 723133, W Bengal, India; [Ranjani, Anandan; Gayathri, Loganathan; Saha, Subhasish; Dhanasekaran, Dharumadurai] Bharathidasan Univ, Dept Microbiol, Tiruchchirappalli 620024, Tamil Nadu, India; [Gayathri, Loganathan; Akbarsha, Mohammad Abdulkader] Bharathidasan Univ, Mahatma Gandhi Doerenkamp Ctr, Tiruchchirappalli 620024, Tamil Nadu, India; [Pasan, Jorge] Univ Valencia, Inst Ciencia Mol ICMol, Catedrat Jose Beltran 2, Valencia 46980, Spain; [Maji, Milan] Natl Inst Technol, Dept Chem, Mahatma Gandhi Ave, Durgapur 713209, W Bengal, India; [Saha, Subhasish] Chinese Acad Sci, South China Sea Inst Oceanol, Ctr Marine Microbiol, Guangzhou 510301, Guangdong, Peoples R China ; LMB
KeywordCobalt(Iii) Crystal Structure Supramolecular Chemistry Anticancer Activity Molecular Docking
Subject AreaChemistry
Document Type期刊论文
Identifierhttp://ir.scsio.ac.cn/handle/344004/15266
Collection中科院海洋生物资源可持续利用重点实验室
Corresponding AuthorBiswas, B (reprint author), Raghunathpur Coll, Dept Chem, Purulia 723133, W Bengal, India.
Recommended Citation
GB/T 7714
Das, Subrata,Ranjani, Anandan,Gayathri, Loganathan,et al. Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity[J]. JOURNAL OF CHEMICAL SCIENCES,2016,128(11):1755-1764.
APA Das, Subrata.,Ranjani, Anandan.,Gayathri, Loganathan.,Saha, Subhasish.,Pasan, Jorge.,...&Biswas, B .(2016).Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity.JOURNAL OF CHEMICAL SCIENCES,128(11),1755-1764.
MLA Das, Subrata,et al."Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2(')-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking and anticancer activity".JOURNAL OF CHEMICAL SCIENCES 128.11(2016):1755-1764.
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