An unusual 1(10 -> 19)abeo steroid from a jellyfish-derived fungus
La Kim, Eun; Li, Jian Lin; Hong, Jongki; Yoon, Won Duk; Kim, Hyung Sik; Liu, Yonghong; Wei, Xiaoyi; Jung, Jee H.; Jung, JH (reprint author), Pusan Natl Univ, Coll Pharm, Busan 609735, South Korea.
2016
发表期刊TETRAHEDRON LETTERS
卷号57期号:25页码:2803-2806
摘要A structurally unique C-25 steroid (phomarol) was isolated from a cultured fungus (Phoma sp.) derived from the giant jellyfish Nemopilema nomurai. Its planar structure and relative configuration were established by analyzing 1D and 2D NMR data, and its absolute configuration was determined using the modified Mosher's method and ECD calculation. Phomarol is unique with a 7-membered carbocyclic A ring [1(10 -> 19)abeo], an aromatic B ring, and a side chain cyclized to form a fused pentacyclic skeleton. (C) 2016 Elsevier Ltd. All rights reserved.
部门归属[La Kim, Eun; Jung, Jee H.] Pusan Natl Univ, Coll Pharm, Busan 609735, South Korea; [Li, Jian Lin] Nantong Univ, Nantong 226001, Jiangsu, Peoples R China; [Hong, Jongki] Kyung Hee Univ, Coll Pharm, Seoul 130701, South Korea; [Yoon, Won Duk] Natl Fisheries Res & Dev Inst, Busan 619705, South Korea; [Kim, Hyung Sik] Sungkyunkwan Univ, Sch Pharm, Suwon 440746, South Korea; [Liu, Yonghong] Chinese Acad Sci, South China Sea Inst Oceanol, Guangzhou 510301, Guangdong, Peoples R China; [Wei, Xiaoyi] Chinese Acad Sci, South China Bot Garden, Guangzhou 510650, Guangdong, Peoples R China ; LMB
关键词Sterol Phoma Sp. Jellyfish-derived Fungus
学科领域Chemistry
文献类型期刊论文
条目标识符http://ir.scsio.ac.cn/handle/344004/15396
专题中科院海洋生物资源可持续利用重点实验室
通讯作者Jung, JH (reprint author), Pusan Natl Univ, Coll Pharm, Busan 609735, South Korea.
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GB/T 7714
La Kim, Eun,Li, Jian Lin,Hong, Jongki,et al. An unusual 1(10 -> 19)abeo steroid from a jellyfish-derived fungus[J]. TETRAHEDRON LETTERS,2016,57(25):2803-2806.
APA La Kim, Eun.,Li, Jian Lin.,Hong, Jongki.,Yoon, Won Duk.,Kim, Hyung Sik.,...&Jung, JH .(2016).An unusual 1(10 -> 19)abeo steroid from a jellyfish-derived fungus.TETRAHEDRON LETTERS,57(25),2803-2806.
MLA La Kim, Eun,et al."An unusual 1(10 -> 19)abeo steroid from a jellyfish-derived fungus".TETRAHEDRON LETTERS 57.25(2016):2803-2806.
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