New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021
Sun, Yu-Lin; Zhang, Xiao-Yong; Nong, Xu-Hua; Xu, Xin-Ya; Qi, Shu-Hua; Qi, SH (reprint author), Chinese Acad Sci, Key Lab Marine Bioresources Sustainable Utilizat, Guangdong Key Lab Marine Mat Med, RNAM Ctr Marine Microbiol,South China Sea Inst Oc, 164 West Xingang Rd, Guangzhou 510301, Guangdong, Peoples R China.
2016
发表期刊TETRAHEDRON LETTERS
卷号57期号:3页码:366-370
摘要A new symmetric 16-membered macrodiolide, trichobotryside A (1), and two new asymmetric 18-membered macrodiolides trichobotrysides B-C (2-3) were obtained from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021. Their structures were elucidated by extensive spectroscopic analysis. The absolute configurations of 1 and 2 were established by the methanolysis and modified Mosher method. And the methanolysis of both 1 and 2 produced the new compound of 4R,7S,9S-trihydroxyl-2en-1-methyl decanoate (4). It was rare to obtain an 18-membered macrodiolide from nature. Compound 1 showed strong antifouling activity against Bugula neritina and Balanus amphitrite larvae settlement. (C) 2015 Elsevier Ltd. All rights reserved.
部门归属[Zhang, Xiao-Yong; Nong, Xu-Hua; Xu, Xin-Ya; Qi, Shu-Hua] Chinese Acad Sci, Key Lab Marine Bioresources Sustainable Utilizat, Guangdong Key Lab Marine Mat Med, RNAM Ctr Marine Microbiol,South China Sea Inst Oc, 164 West Xingang Rd, Guangzhou 510301, Guangdong, Peoples R China; [Sun, Yu-Lin] Lingnan Normal Univ, Life Sci & Technol Sch, Zhanjiang 524048, Peoples R China ; LMB
关键词Deep-sea-derived Fungus Trichobotrys Effuse Macrodiolide Trichobotrysides A-c Absolute Configuration Antifouling
学科领域Chemistry
文献类型期刊论文
条目标识符http://ir.scsio.ac.cn/handle/344004/15505
专题中科院海洋生物资源可持续利用重点实验室
通讯作者Qi, SH (reprint author), Chinese Acad Sci, Key Lab Marine Bioresources Sustainable Utilizat, Guangdong Key Lab Marine Mat Med, RNAM Ctr Marine Microbiol,South China Sea Inst Oc, 164 West Xingang Rd, Guangzhou 510301, Guangdong, Peoples R China.
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Sun, Yu-Lin,Zhang, Xiao-Yong,Nong, Xu-Hua,et al. New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021[J]. TETRAHEDRON LETTERS,2016,57(3):366-370.
APA Sun, Yu-Lin,Zhang, Xiao-Yong,Nong, Xu-Hua,Xu, Xin-Ya,Qi, Shu-Hua,&Qi, SH .(2016).New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021.TETRAHEDRON LETTERS,57(3),366-370.
MLA Sun, Yu-Lin,et al."New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021".TETRAHEDRON LETTERS 57.3(2016):366-370.
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