Synergistic reduction of copper (II) and oxidation of norfloxacin over a novel sewage sludge-derived char-based catalyst: Performance, fate and mechanism
Liu, JJ; Diao, ZH; Liu, CM; Jiang, D; Kong, LJ; Xu, XR; zenghuid86@scsio.ac.cn; xuxr@scsio.ac.cn
2018
发表期刊JOURNAL OF CLEANER PRODUCTION
卷号182页码:794-804
摘要Nowadays, clean-up of waters with coexisting heavy metal ions and organic pollutants is of great environmental importance. In this study, a novel sewage sludge-derived char-based catalyst was firstly synthesized, and coupled with hydrogen peroxide for the simultaneous removal of copper (11) and norfloxacin in aqueous solutions. The most relevant findings revealed that zero-valent iron and zero-valent aluminum particles were successfully formed on the catalyst surface when the leaching of the sludge-derived char was reduced by the green tea extract. Nearly 100% of both copper (11) and norfloxacin were simultaneously removed due to a synergistic effect between the reduction of copper (11) and the oxidation of norfloxacin over the catalyst. The gradual addition mode of hydrogen peroxide exhibited a better performance on the simultaneous removal of copper (11) and norfloxacin. The coexisting anions like nitrate and phosphate had significant negative effects on the copper (11) removal, whereas carbonate, fluoride and phosphate had significant negative effects on the norfloxacin removal. Different copper species like zero-valent copper, copper oxide and copper hydroxide were identified in copper (11: reduction process, whereas a total of eight oxidative products were identified in norfloxacin oxidation process. A possible reaction mechanism for the simultaneous removal of copper (II) and norfloxacin by the sewage sludge-derived char-based catalyst/hydrogen peroxide system was proposed. The adsorption of both copper (II) and norfloxacin over the catalyst were firstly occurred, and then the reduction of copper (II) over both zero-valent iron and zero-valent aluminum particles on the catalyst surface as well as the Fenton oxidation of norfloxacin were followed. (C) 2018 Elsevier Ltd. All rights reserved.
部门归属[Liu, Jin-Jun; Diao, Zeng-Hui; Liu, Cui-Mei; Xu, Xiang-Rong] Chinese Acad Sci, South China Sea Inst Oceanol, Guangdong Prov Key Lab Appl Marine Biol, CAS Key Lab Trop Marine Bioresources & Ecol, Guangzhou 510301, Guangdong, Peoples R China; [Liu, Jin-Jun] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Jiang, Dan] South China Normal Univ, Res Resources Ctr, Guangzhou 510631, Guangdong, Peoples R China; [Kong, Ling-Jun] Guangzhou Univ, Sch Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China
学科领域Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology
关键词[WOS]Copper (II) ; Norfloxacin ; Zero-valent iron ; Zero-valent aluminum ; Sewage sludge-derived char ; Simultaneous removal
资助项目LMB
文献类型期刊论文
条目标识符http://ir.scsio.ac.cn/handle/344004/16963
专题中科院海洋生物资源可持续利用重点实验室
通讯作者zenghuid86@scsio.ac.cn; xuxr@scsio.ac.cn
推荐引用方式
GB/T 7714
Liu, JJ,Diao, ZH,Liu, CM,et al. Synergistic reduction of copper (II) and oxidation of norfloxacin over a novel sewage sludge-derived char-based catalyst: Performance, fate and mechanism[J]. JOURNAL OF CLEANER PRODUCTION,2018,182:794-804.
APA Liu, JJ.,Diao, ZH.,Liu, CM.,Jiang, D.,Kong, LJ.,...&xuxr@scsio.ac.cn.(2018).Synergistic reduction of copper (II) and oxidation of norfloxacin over a novel sewage sludge-derived char-based catalyst: Performance, fate and mechanism.JOURNAL OF CLEANER PRODUCTION,182,794-804.
MLA Liu, JJ,et al."Synergistic reduction of copper (II) and oxidation of norfloxacin over a novel sewage sludge-derived char-based catalyst: Performance, fate and mechanism".JOURNAL OF CLEANER PRODUCTION 182(2018):794-804.
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