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学科主题: Crystallography
题名: Xyloccensin L
作者: Feng, G ; Zhang, J ; Li, J ; Satyanandamurty, T ; Wu, J
通讯作者: feng8513@sina.com ; wwujun2003@yahoo.com
刊名: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
发表日期: 2010
卷: 66, 页:O2111-U2003
收录类别: sci
部门归属: [Feng, Gang; Zhang, Jing] Chinese Acad Trop Agr Sci, Environm & Plant Protect Inst, Danzhou 571737, Peoples R China; [Li, Jun; Wu, Jun] Chinese Acad Sci, S China Sea Inst Oceanol, Key Lab Marine Bioresources Sustainable Utilizat, Guangzhou 510301, Guangdong, Peoples R China; [Satyanandamurty, Tirumani] Govt Degree Coll, Amadala Valasa 532185, Andhra Pradesh, India
项目归属: LMB
摘要: The title compound, C32H40O10, also known as xyloccensin L [systematic name: (1R,4aR,4bS,5aR,6aR,9R,10S,10aS,10bR,2aR,13R)-1-(furan-3-yl)-6a-hydroxy-10-(2-methoxy-2-oxoethyl)-9,10a,12a-trimethyl-3-oxododecahydro-1H,3H,5aH-6,9-methanoisochromeno[6,5-f]oxireno[g]chromen-13-yl (2E)-2-methylbut-2-enoate], is a limonoid with a C1-C29 oxygen bridge: this is the first report of the X-ray crystal structure of such a limonoid. Two fused pyran rings and two cyclohexane rings adopt boat conformations, while another cyclohexane ring and the d-lactone ring are in half-chair conformations. The molecular structure is stabilized by intramolecular O-H...O hydrogen bonding.
原文出处: 查看原文
WOS记录号: WOS:000282468900181
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内容类型: 期刊论文
URI标识: http://ir.scsio.ac.cn/handle/344004/3760
Appears in Collections:中科院海洋生物资源可持续利用重点实验室_期刊论文

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Feng, G; Zhang, J; Li, J; Satyanandamurty, T; Wu, J.Xyloccensin L,ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE,2010,66():O2111-U2003
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