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学科主题: Crystallography
题名: {mu-6,6 '-dimethoxy-2,2 '-[1,2-phenylene-bis(nitrilomethylidyne)]diphenolato}-methanolcopper(II)sodium(I)
作者: Bian, J
通讯作者: jiangbian2008@yahoo.cn
刊名: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
发表日期: 2008
卷: 64, 页:M625-U202
收录类别: sci
部门归属: [Bian, Jiang] Chinese Acad Sci, S China Sea Inst Oceanol, Guangzhou 510301, Guangdong, Peoples R China; [Bian, Jiang] Chinese Acad Sci, Inst Microbiol, Beijing 100101, Peoples R China; [Bian, Jiang] Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China
摘要: In the title complex, [NaCu(C22H18N2O4)Cl(CH3OH)], the Cu atom lies nearly in the plane defined by the N2O2 core of donor atoms, the out-of-plane distance being 0.001 (2) angstrom. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [ maximum displacement from the mean plane through the five atoms = 0.152 (3) angstrom for Na]. The crystal structure is stabilized by intermolecular C H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds, which link the molecules into dimers. The crystal packing is further stabilized by weak pi-pi stacking interactions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) angstrom].
原文出处: 查看原文
WOS记录号: WOS:000255450100020
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内容类型: 期刊论文
URI标识: http://ir.scsio.ac.cn/handle/344004/5366
Appears in Collections:海洋生物_期刊论文

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Bian, J.{mu-6,6 '-dimethoxy-2,2 '-[1,2-phenylene-bis(nitrilomethylidyne)]diphenolato}-methanolcopper(II)sodium(I),ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE,2008,64():M625-U202
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