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{mu-6,6 '-dimethoxy-2,2 '-[1,2-phenylene-bis(nitrilomethylidyne)]diphenolato}-methanolcopper(II)sodium(I)
Bian, J; jiangbian2008@yahoo.cn
2008
Source PublicationACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN1600-5368
Volume64Pages:M625-U202
AbstractIn the title complex, [NaCu(C22H18N2O4)Cl(CH3OH)], the Cu atom lies nearly in the plane defined by the N2O2 core of donor atoms, the out-of-plane distance being 0.001 (2) angstrom. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [ maximum displacement from the mean plane through the five atoms = 0.152 (3) angstrom for Na]. The crystal structure is stabilized by intermolecular C H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds, which link the molecules into dimers. The crystal packing is further stabilized by weak pi-pi stacking interactions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) angstrom].
Department[Bian, Jiang] Chinese Acad Sci, S China Sea Inst Oceanol, Guangzhou 510301, Guangdong, Peoples R China; [Bian, Jiang] Chinese Acad Sci, Inst Microbiol, Beijing 100101, Peoples R China; [Bian, Jiang] Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China
Subject AreaCrystallography
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Indexed Bysci
WOS IDWOS:000255450100020
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Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.scsio.ac.cn/handle/344004/5366
Collection海洋生物
Corresponding Authorjiangbian2008@yahoo.cn
Recommended Citation
GB/T 7714
Bian, J,jiangbian2008@yahoo.cn. {mu-6,6 '-dimethoxy-2,2 '-[1,2-phenylene-bis(nitrilomethylidyne)]diphenolato}-methanolcopper(II)sodium(I)[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE,2008,64:M625-U202.
APA Bian, J,&jiangbian2008@yahoo.cn.(2008).{mu-6,6 '-dimethoxy-2,2 '-[1,2-phenylene-bis(nitrilomethylidyne)]diphenolato}-methanolcopper(II)sodium(I).ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE,64,M625-U202.
MLA Bian, J,et al."{mu-6,6 '-dimethoxy-2,2 '-[1,2-phenylene-bis(nitrilomethylidyne)]diphenolato}-methanolcopper(II)sodium(I)".ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 64(2008):M625-U202.
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