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学科主题: Optics
题名: Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica
作者: Wang, B ; Liu, Y ; Li, B ; Yue, S ; Li, W
通讯作者: lib020@ciomp.ac.cn
关键词: oxygen sensor ; trinuclear starburst Ru(II) complexes ; mesoporous silicate
刊名: JOURNAL OF LUMINESCENCE
发表日期: 2008
卷: 128, 期:3, 页:341-347
收录类别: sci
部门归属: [Wang, Binbin; Li, Bin; Yue, Shumei; Li, Wenlian] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China; [Wang, Binbin] NE Normal Univ, Dept Chem, Minist Educ, Polyoxometalate Sci Key Lab, Changchun 130024, Peoples R China; [Liu, Yana] Chinese Acad Sci, S China Inst Oceanol, Key Lab Trop Marine Environm Dynam, Guangzhou 510301, Peoples R China
项目归属: LED
摘要: The preparation and oxygen sensing properties of optical materials based on two trinuclear starburst ruthenium(II) complexes: [Ru-3(bpy)(6)(TMMB)](6+) (1) and [Ru-3(phen)(6)(TMMB)](6+) (2) (bpy = 2,2'-bpyridine, phen = 1, 10-phenathroline, TMMB = 1,3,5-tris [2-(2'-pyridyl)benzimidazoyl]methylbenzene) assembled in two mesoporous silicate (MS) are described in this paper. The luminescence of Ru complexes/silicate assemble materials can be quenched by molecular oxygen with good sensitivity (I-0/I-1 > 5 for 2/MS and I-0/I-1 > 3 for 1/MS), indicating that trinuclear starburst Ru(II) complexes/MS systems are sensitive to oxygen molecules. (C) 2007 Elsevier B.V. All rights reserved.
原文出处: 查看原文
WOS记录号: WOS:000252566300012
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内容类型: 期刊论文
URI标识: http://ir.scsio.ac.cn/handle/344004/6037
Appears in Collections:热带海洋环境动力实验室(LTO)_期刊论文

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Wang, B; Liu, Y; Li, B; Yue, S; Li, W.Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica,JOURNAL OF LUMINESCENCE,2008,128(3):341-347
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文件名: Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica .pdf
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