Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica
Wang, B; Liu, Y; Li, B; Yue, S; Li, W; lib020@ciomp.ac.cn
2008
发表期刊JOURNAL OF LUMINESCENCE
ISSN0022-2313
卷号128期号:3页码:341-347
摘要The preparation and oxygen sensing properties of optical materials based on two trinuclear starburst ruthenium(II) complexes: [Ru-3(bpy)(6)(TMMB)](6+) (1) and [Ru-3(phen)(6)(TMMB)](6+) (2) (bpy = 2,2'-bpyridine, phen = 1, 10-phenathroline, TMMB = 1,3,5-tris [2-(2'-pyridyl)benzimidazoyl]methylbenzene) assembled in two mesoporous silicate (MS) are described in this paper. The luminescence of Ru complexes/silicate assemble materials can be quenched by molecular oxygen with good sensitivity (I-0/I-1 > 5 for 2/MS and I-0/I-1 > 3 for 1/MS), indicating that trinuclear starburst Ru(II) complexes/MS systems are sensitive to oxygen molecules. (C) 2007 Elsevier B.V. All rights reserved.
部门归属[Wang, Binbin; Li, Bin; Yue, Shumei; Li, Wenlian] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China; [Wang, Binbin] NE Normal Univ, Dept Chem, Minist Educ, Polyoxometalate Sci Key Lab, Changchun 130024, Peoples R China; [Liu, Yana] Chinese Acad Sci, S China Inst Oceanol, Key Lab Trop Marine Environm Dynam, Guangzhou 510301, Peoples R China
关键词Oxygen Sensor Trinuclear Starburst Ru(Ii) Complexes Mesoporous Silicate
学科领域Optics
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收录类别sci
资助项目LED
WOS记录号WOS:000252566300012
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文献类型期刊论文
条目标识符http://ir.scsio.ac.cn/handle/344004/6037
专题热带海洋环境国家重点实验室(LTO)
通讯作者lib020@ciomp.ac.cn
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Wang, B,Liu, Y,Li, B,et al. Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica[J]. JOURNAL OF LUMINESCENCE,2008,128(3):341-347.
APA Wang, B,Liu, Y,Li, B,Yue, S,Li, W,&lib020@ciomp.ac.cn.(2008).Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica.JOURNAL OF LUMINESCENCE,128(3),341-347.
MLA Wang, B,et al."Optical oxygen sensing materials based on trinuclear starburst ruthenium(II) complexes assembled in mesoporous silica".JOURNAL OF LUMINESCENCE 128.3(2008):341-347.
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