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学科主题: Chemistry, Organic
题名: Carboxyl Formation from Methyl via Triple Hydroxylations by XiaM in Xiamycin A Biosynthesis
其他题名: mannual of IR1
作者: Zhang, QB ; Li, HX ; Li, SM ; Zhu, YG ; Zhang, GT ; Zhang, HB ; Zhang, WJ ; Shi, R ; Zhang, CS
通讯作者: czhang2006@gmail.com
刊名: ORGANIC LETTERS
发表日期: 2012
卷: 14, 期:24, 页:6142-6145
收录类别: sci
合作性质: 填入合作性质等
部门归属: [Zhang, Qingbo; Li, Huixian; Li, Sumei; Zhu, Yiguang; Zhang, Guangtao; Zhang, Haibo; Zhang, Wenjun; Zhang, Changsheng] Chinese Acad Sci, CAS Key Lab Marine Bioresources Sustainable Utili, Guangdong Key Lab Marine Mat Med, RNAM Ctr Marine Microbiol,S China Sea Inst Oceano, Guangzhou 510301, Guangdong, Peoples R China; [Zhang, Qingbo] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China; [Shi, Rong] Univ Laval, Dept Biochimie Microbiol & Bioinformat, PROTEO & IBIS, Quebec City, PQ G1V 0A6, Canada
项目归属: LMB
产权排名: 产权排序
资助者: 国科图
摘要: The P450 enzyme XiaM was identified as a candidate to form the C-24 carboxyl group in xiamycin A (1). Alteration of medium composition led to the discovery of four new compounds from the Delta xiaM and the Delta xiaK (encoding an aromatic ring hydroxylase) mutants. Biotransformation experiments revealed that XiaM was capable of converting a methyl group to a carboxyl group through diol and aldehyde intermediates.
英文摘要: description.abstract
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000312564500007
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.scsio.ac.cn/handle/344004/9728
Appears in Collections:中科院海洋生物资源可持续利用重点实验室_期刊论文

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Recommended Citation:
Zhang, QB; Li, HX; Li, SM; Zhu, YG; Zhang, GT; Zhang, HB; Zhang, WJ; Shi, R; Zhang, CS.Carboxyl Formation from Methyl via Triple Hydroxylations by XiaM in Xiamycin A Biosynthesis,ORGANIC LETTERS,2012,14(24):6142-6145
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