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Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis
Li, J; Li, MY; Bruhn, T; Gotz, DCG; Xiao, Q; Satyanandamurty, T; Wu, J; Bringmann, G; wwujun2003@yahoo.com; bringmann@chemie.uni-wuerzburg.de
2012
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
Volume18Issue:45Pages:14342-14351
AbstractFive new limonoids, including andhraxylocarpins A and B (1 and 2) which contain a 9-oxa-tricyclo[3.3.2.17,?10]undecane-2-ene motif, andhraxylocarpins C and D (3 and 4), which contain a (Z)-bicyclo[5.2.1]dec-3-en-8-one substructure, and andhraxylocarpin E (5), which contains a tricyclo[3.3.1.13,?6]decane-9-one scaffold, were isolated from the seeds of two true mangroves, Xylocarpus granatum and Xylocarpus moluccensis, that were collected in the estuaries of Andhra Pradesh, India. The absolute configurations of these compounds were determined by extensive NMR investigations, single-crystal X-ray diffraction analysis, and by circular dichroism and optical rotatory dispersion spectroscopy, in combination with quantum-chemical calculations. The pronounced structural diversity of limonoids from these mangroves might originate from environmental factors.
Department[Li, Jun; Li, Min-Yi; Wu, Jun] Chinese Acad Sci, S China Sea Inst Oceanol, Key Lab Marine Bioresources Sustainable Utilizat, Guangzhou 510301, Guangdong, Peoples R China; [Bruhn, Torsten; Goetz, Daniel C. G.; Bringmann, Gerhard] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany; [Xiao, Qiang] Jiangxi Sci & Technol Normal Univ, Inst Organ Chem, Nanchang 330013, Peoples R China; [Li, Jun] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China; [Satyanandamurty, Tirumani] Govt Degree Coll Amadala Valasa, Srikakulam 532185, Andhra Pradesh, India
KeywordConfiguration Determination Limonoids Natural Products True Mangroves X-ray Diffraction
Subject AreaChemistry, Multidisciplinary
Language英语
Funding ProjectLMB
WOS IDWOS:000310474800018
Citation statistics
Document Type期刊论文
Identifierhttp://ir.scsio.ac.cn/handle/344004/9758
Collection中科院海洋生物资源可持续利用重点实验室
Corresponding Authorwwujun2003@yahoo.com; bringmann@chemie.uni-wuerzburg.de
Recommended Citation
GB/T 7714
Li, J,Li, MY,Bruhn, T,et al. Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis[J]. CHEMISTRY-A EUROPEAN JOURNAL,2012,18(45):14342-14351.
APA Li, J.,Li, MY.,Bruhn, T.,Gotz, DCG.,Xiao, Q.,...&bringmann@chemie.uni-wuerzburg.de.(2012).Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis.CHEMISTRY-A EUROPEAN JOURNAL,18(45),14342-14351.
MLA Li, J,et al."Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis".CHEMISTRY-A EUROPEAN JOURNAL 18.45(2012):14342-14351.
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