Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis
Li, J; Li, MY; Bruhn, T; Gotz, DCG; Xiao, Q; Satyanandamurty, T; Wu, J; Bringmann, G; wwujun2003@yahoo.com; bringmann@chemie.uni-wuerzburg.de
2012
发表期刊CHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
卷号18期号:45页码:14342-14351
摘要Five new limonoids, including andhraxylocarpins A and B (1 and 2) which contain a 9-oxa-tricyclo[3.3.2.17,?10]undecane-2-ene motif, andhraxylocarpins C and D (3 and 4), which contain a (Z)-bicyclo[5.2.1]dec-3-en-8-one substructure, and andhraxylocarpin E (5), which contains a tricyclo[3.3.1.13,?6]decane-9-one scaffold, were isolated from the seeds of two true mangroves, Xylocarpus granatum and Xylocarpus moluccensis, that were collected in the estuaries of Andhra Pradesh, India. The absolute configurations of these compounds were determined by extensive NMR investigations, single-crystal X-ray diffraction analysis, and by circular dichroism and optical rotatory dispersion spectroscopy, in combination with quantum-chemical calculations. The pronounced structural diversity of limonoids from these mangroves might originate from environmental factors.
部门归属[Li, Jun; Li, Min-Yi; Wu, Jun] Chinese Acad Sci, S China Sea Inst Oceanol, Key Lab Marine Bioresources Sustainable Utilizat, Guangzhou 510301, Guangdong, Peoples R China; [Bruhn, Torsten; Goetz, Daniel C. G.; Bringmann, Gerhard] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany; [Xiao, Qiang] Jiangxi Sci & Technol Normal Univ, Inst Organ Chem, Nanchang 330013, Peoples R China; [Li, Jun] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China; [Satyanandamurty, Tirumani] Govt Degree Coll Amadala Valasa, Srikakulam 532185, Andhra Pradesh, India
关键词Configuration Determination Limonoids Natural Products True Mangroves X-ray Diffraction
学科领域Chemistry, Multidisciplinary
语种英语
资助项目LMB
WOS记录号WOS:000310474800018
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.scsio.ac.cn/handle/344004/9758
专题中科院海洋生物资源可持续利用重点实验室
通讯作者wwujun2003@yahoo.com; bringmann@chemie.uni-wuerzburg.de
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GB/T 7714
Li, J,Li, MY,Bruhn, T,et al. Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis[J]. CHEMISTRY-A EUROPEAN JOURNAL,2012,18(45):14342-14351.
APA Li, J.,Li, MY.,Bruhn, T.,Gotz, DCG.,Xiao, Q.,...&bringmann@chemie.uni-wuerzburg.de.(2012).Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis.CHEMISTRY-A EUROPEAN JOURNAL,18(45),14342-14351.
MLA Li, J,et al."Andhraxylocarpins A-E: Structurally Intriguing Limonoids from the True Mangroves Xylocarpus granatum and Xylocarpus moluccensis".CHEMISTRY-A EUROPEAN JOURNAL 18.45(2012):14342-14351.
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